Thermodynamic study of binary mixtures of toluene with ionic liquids, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide
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چکیده
منابع مشابه
Density, Viscosity and Surface Tension of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Tricyanomethanide with Benzothiophene
The effects of temperature and composition on the density and viscosity of pure benzothiophene and ionic liquid (IL), and those of the binary mixtures containing the IL 1-butyl-1-methylpyrrolidynium tricyanomethanide ([BMPYR][TCM] + benzothiophene), are reported at six temperatures (308.15, 318.15, 328.15, 338.15, 348.15 and 358.15) K and ambient pressure. The temperature dependences of the den...
متن کاملPhase Behaviour and FTIR Spectra of Ionic Liquids: The Mixtures of 1-Butyl-1-methylpyrrolidinium Chloride and TaCl5
A series of ionic liquids consisting of 1-butyl-1-methylpyrrolidinium chloride (Pyr14Cl) and TaCl5 at molar ratios of Pyr14Cl in the range of 0.85 – 0.20 was synthesized. They exhibit potential application as electrolytes for the electrochemical deposition of tantalum. The thermal behaviour of the Pyr14Cl-TaCl5 mixtures was investigated, using differential scanning calorimetry (DSC) to estimate...
متن کاملElectrodeposition of germanium from the ionic liquid 1-butyl-1-methylpyrrolidinium dicyanamide.
The electrodeposition of germanium from the ionic liquid 1-butyl-1-methylpyrrolidinium dicyanamide ([BMP][DCA]) and a mixture of [BMP][DCA] and 1-butyl-1-methylpyrrolidinium chloride ([BMP]Cl) was studied using cyclic voltammetry and using an electrochemical quartz crystal microbalance (EQCM). [GeCl4(BuIm)2] (BuIm = N-butylimidazole) was used as germanium source as it has a solubility of 0.47 M...
متن کاملSpectroscopy and Electrochemistry of Tantalum(V) in 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate
FTIR spectroscopic and electrochemical characterizations of tantalum(V) in 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate (Pyr14TFMS)-TaCl5 ionic liquids are performed with 5, 15, and 35 mol% TaCl5 as the media for potential electrochemical application. On the basis of FTIR spectra the electrochemical active species are identified as follows: [TaOCl4]−, [TaOCl5]2−, [TaCl5F]−, and [TaCl...
متن کاملLiTFSI in 1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)amide: a possible electrolyte for ionic liquid based lithium ion batteries.
In this communication, we show that the combination of 1 M lithium bis(trifluoromethylsulfonyl)amide and 1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)amide (LiTFSI/[Py1,4]FSI) can be regarded as a possible stable electrolyte for IL based lithium ion batteries. We compare the charge-discharge results with the electrolyte 1 M LiTFSI in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl...
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ژورنال
عنوان ژورنال: Journal of Molecular Liquids
سال: 2020
ISSN: 0167-7322
DOI: 10.1016/j.molliq.2020.112754